On the dashboard, click +NEW JOB:
Select "With a Request-to-hire":
In the pop-up, select the correct requisition form to use and click Create:
Fill in all the mandatory fields (marked with a red asterisk *) in the form that is generated:
Scroll down to the Approval Workflow. This shows how the form will be sent through your organisation for the approval process. Some of the approvers will automatically be chosen, and some will need to be chosen manually by you.
Once all mandatory fields have been completed, submit for approval by clicking the button at the bottom of the page.
Hope this helps!